A study of MR signal reception from a model for a battery cell.

Number of NMR/MRI studies on batteries is rapidly increasing in the past decade. As the test batteries designed for the studies contain metal parts such as electrodes and lead wires as well as other conductive parts (electrolyte), which all present obstacles for good MR signal reception, understanding of the role of battery design and of battery interactions with magnetic field is of a key importance for a successful performance of the experiments. For the study, five different samples mimicking a real battery cell were made. All the samples had two parallel copper electrodes separated by a gel layer, however, they differed in electrode thickness, gel conductivity and separation between the electrodes. The samples were inserted in an MRI magnet in different orientations with respect to magnetic fields B and B and scanned with the spin-echo and single point imaging methods in 2D and 3D (spin-echo only). The performed experiments confirmed that the main reason for poor MR signal reception from a test battery are RF-induced eddy currents. These were found stronger with the sample with the smaller distance between the electrodes. The effect of RF-induced eddy currents was efficiently suppressed when the sample was oriented with the electrodes parallel to the B field. However, in the orientation there were still susceptibility effects that caused a signal voiding in a narrow region near the electrodes. The susceptibility effects were found lower with the sample with thin electrodes and the non-conductive gel. The results of the study can help optimizing test battery and capacitor designs for NMR/MRI experiments.