Shenzhen Key Laboratory of Circular Economy, Shenzhen Graduate School, Peking University, Shenzhen 518055, China.
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.
Chemosphere. 2018 Oct;209:707-720. doi: 10.1016/j.chemosphere.2018.06.095. Epub 2018 Jun 21.
Since the creation of first man-made plastic, the global production and consumption of plastics have been continuously increasing. However, because plastic materials are durable and very slow to degrade, they become waste with high staying power. The over-consumption, disposal, and littering of plastics result in pollution, thus causing serious environmental consequences. To date, only a fraction of waste plastics is reused and recycled. In fact, recycling plastics remains a great challenge because of technical challenges and relatively insufficient profits, especially in mixed plastics. This review focuses on an environmentally friendly and potentially profitable method for plastics separation and recovery and solvents extraction. It includes the dissolution/reprecipitation method and supercritical fluid extraction, which produce high-quality recovered plastics comparable to virgin materials. These methods are summarized and discussed taking mass-produced plastics (PS, PC, Polyolefins, PET, ABS, and PVC) as examples. To exploit the method, the quality and efficiency of solvent extraction are elaborated. By eliminating these technical challenges, the solvent extraction method is becoming more promising and sustainable for plastic issues and polymer markets.
自第一种人造塑料问世以来,塑料的全球产量和消费量一直在持续增长。然而,由于塑料材料耐用且降解速度非常缓慢,它们变成了具有高持久力的废物。塑料的过度消费、处置和乱扔导致了污染,从而造成了严重的环境后果。迄今为止,只有一小部分废塑料被再利用和回收。事实上,由于技术挑战和相对不足的利润,尤其是在混合塑料中,回收塑料仍然是一个巨大的挑战。
本综述重点介绍了一种环保且具有潜在利润的塑料分离和回收以及溶剂提取方法。它包括溶解/沉淀法和超临界流体萃取法,这两种方法可生产出与原始材料相当的高质量回收塑料。这些方法以大规模生产的塑料(PS、PC、聚烯烃、PET、ABS 和 PVC)为例进行了总结和讨论。为了利用该方法,详细阐述了溶剂萃取的质量和效率。通过消除这些技术挑战,溶剂萃取方法在解决塑料问题和聚合物市场方面变得更有前途和可持续。