A Nanosized Phenylene-Ethynylene-Butadiynylene [2]Catenane.

In a convergent, template-directed synthesis, an efficient route to a phenylene-ethynylene-butadiynylene based [2]catenane is described. The key step is performed by the aminolysis of the corresponding precatenane, which is obtained by a sequence of metal-catalyzed cross-coupling and desilylation reactions. The cyclization reaction leads besides the [2]precatenane to a variety of larger precatenanes and offers an attractive approach to mechanically interlocked structures of different size.