Wang Jun-Xia, Gu Hai-Dong, Zhang Zhan-En, Qian Fei-Yue
School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China.
Jiangsu Key Laboratory of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China.
Huan Jing Ke Xue. 2018 Apr 8;39(4):1544-1551. doi: 10.13227/j.hjkx.201708147.
Eight polybrominated diphenyl ether (PBDE) congeners in indoor and outdoor air particles were collected using higher-volume active sampling techniques from different functional areas, including an industrial workplace, office, domestic area, and scenic area in an industrial zone, in Suzhou city, and the samples were analyzed by GC-MS. The total concentration of PBDEs ranged from 9.22-64.15 pg·m (average 20.93 pg·m), and 1.06-8.44 pg·m(average 5.11 pg·m)in indoor and outdoor air, respectively. The results showed that the concentrations of PBDEs in indoor PM was significantly higher than that in the outdoor PM. The average concentrations of PBDEs in the air of the different sampling areas were in the order:industrial workplace<office<dwelling indoor<outdoor air. Compared with the concentrations of PBDEs in the indoor and outdoor particulate matters from other regions, the concentrations of PBDEs in the indoor and outdoor atmospheric particles from Suzhou were at lower levels. BDE-209 was the most abundant (average 63% of the total PBDEs) in indoor and outdoor air, followed by BDE-99 and BDE-47.The estimated daily intake of PBDEs via inhalation was 3.75, 2.78, and 2.60 pg·(kg·d) by the workers in the workplace, workers in office, and toddlers, respectively. Results showed that inhalation exposure to PBDEs did not cause potential health risks in the local residents of Suzhou.
采用大容量主动采样技术,在苏州市某工业区的不同功能区域(包括工业工作场所、办公室、居民区和风景区)采集室内和室外空气颗粒物中的8种多溴二苯醚(PBDE)同系物,并通过气相色谱 - 质谱联用仪(GC - MS)对样品进行分析。PBDEs的总浓度在室内空气中为9.22 - 64.15 pg·m³(平均20.93 pg·m³),在室外空气中为1.06 - 8.44 pg·m³(平均5.11 pg·m³)。结果表明,室内颗粒物中PBDEs的浓度显著高于室外颗粒物中的浓度。不同采样区域空气中PBDEs的平均浓度顺序为:工业工作场所<办公室<室内住宅<室外空气。与其他地区室内和室外颗粒物中PBDEs的浓度相比,苏州室内和室外大气颗粒物中PBDEs的浓度处于较低水平。BDE - 209在室内和室外空气中含量最高(平均占总PBDEs的63%),其次是BDE - 99和BDE - 47。通过吸入途径,工作场所的工人、办公室工作人员和幼儿每天摄入PBDEs的估计量分别为3.75、2.78和2.60 pg·(kg·d)。结果表明,吸入PBDEs不会对苏州当地居民造成潜在健康风险。