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碳源胁迫下生物脱氮除磷颗粒污泥的特性及机制

[Characteristics and Mechanism of Biological Nitrogen and Phosphorus Removal Granular Sludge Under Carbon Source Stress].

作者信息

Qin Shi-You, Chen Wei, Ma Zhao-Rui, Liu Xiao-Ying, Chen Xiao-Guo, Yu Wen-Tao, Xia Yuan-Yuan, Huang Jian

机构信息

School of Urban Construction, Wuhan University of Science and Technology, Wuhan 430065, China.

School of Civil Engineering & Architecture, Wuhan University of Technology, Wuhan 430070, China.

出版信息

Huan Jing Ke Xue. 2017 Jun 8;38(6):2461-2469. doi: 10.13227/j.hjkx.201610027.

Abstract

In SBR reactor, the mature granular sludge fed with sodium acetate was gradually cultivated with different carbon sources (sodium acetate/glucose ratio was 1:0, 3:1, 1:1, 1:3 and 0:1, in terms of COD, respectively). During the five stages, the physical, biochemical properties, extracellular polymeric substances (EPS), phosphorus fractions and nitrogen and phosphorus removal efficiency of granular sludge were studied. 705 days' experimental results were showed as follows. At stage Ⅳ, the granular sludge had the smallest diameter of 0.5 mm; moreover the phosphorus release/uptake rate, denitrification rate and the total phosphorus (TP) content were the lowest. While at stages Ⅰ and Ⅱ, the phosphorus release/uptake and denitrification rates were the highest, meanwhile, the TP content reached up to 72.36 mg·g, and the EPS content was about 350 mg·g, as a result, the nitrogen and phosphorus removal efficiencies were both over 94%. Nevertheless at stage Ⅴ, the biochemical rates were slightly slower than values of stages Ⅰ and Ⅱ, simultaneously the TP, glycogen and EPS contents in sludge were maintained at 69.60 mg·g, 224.18 mg·g and 200 mg·g, respectively, while high nitrogen and phosphorus removal efficiency was obtained. During all stages, Ca-P was the main phosphorus fraction, and inorganic phosphorus(IP) was closely related to phosphorus removal of granular sludge.

摘要

在序批式反应器中,以乙酸钠为进水,用不同碳源(乙酸钠与葡萄糖的COD比分别为1:0、3:1、1:1、1:3和0:1)逐步培养成熟的颗粒污泥。在这五个阶段中,研究了颗粒污泥的物理、生化性质、胞外聚合物(EPS)、磷形态以及氮磷去除效率。705天的实验结果如下。在阶段Ⅳ,颗粒污泥直径最小,为0.5毫米;此外,磷的释放/吸收速率、反硝化速率和总磷(TP)含量最低。而在阶段Ⅰ和Ⅱ,磷的释放/吸收和反硝化速率最高,同时TP含量达到72.36毫克/克,EPS含量约为350毫克/克,因此氮磷去除效率均超过94%。然而在阶段Ⅴ,生化速率略低于阶段Ⅰ和Ⅱ,同时污泥中的TP、糖原和EPS含量分别维持在69.60毫克/克、224.18毫克/克和200毫克/克,且获得了较高的氮磷去除效率。在所有阶段中,钙磷是主要的磷形态,无机磷(IP)与颗粒污泥的磷去除密切相关。

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