高价碘（III）试剂促进亚磺酸盐快速转化为磺酸盐。
Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent.
作者信息
Deruer Elsa, Hamel Vincent, Blais Samuel, Canesi Sylvain
机构信息
Laboratoire de Méthodologie et Synthèse de Produits Naturels, Université du Québec à Montréal, C.P. 8888, Succ. Centre-Ville, Montréal, H3C 3P8 Québec, Canada.
出版信息
Beilstein J Org Chem. 2018 May 24;14:1203-1207. doi: 10.3762/bjoc.14.101. eCollection 2018.
An alternative method for forming sulfonates through hypervalent iodine(III) reagent-mediated oxidation of sodium sulfinates has been developed. This transformation involves trapping reactive sulfonium species using alcohols. With additional optimization of the reaction conditions, the method appears extendable to other nucleophiles such as electron-rich aromatic systems or cyclic ethers through a ring opening pathway.
已经开发出一种通过高价碘（III）试剂介导的亚磺酸钠氧化来形成磺酸盐的替代方法。这种转化涉及使用醇捕获活性锍物种。随着反应条件的进一步优化，该方法似乎可以通过开环途径扩展到其他亲核试剂，如富电子芳族体系或环醚。
Zotero 插件