Yoshizawa Akina, Feula Antonio, Leach Andrew G, Male Louise, Fossey John S
School of Chemistry, University of Birmingham, Birmingham, United Kingdom.
School of Pharmacy and Biomolecular Sciences, Liverpool John Moores University, Liverpool, United Kingdom.
Front Chem. 2018 Jun 21;6:211. doi: 10.3389/fchem.2018.00211. eCollection 2018.
Seven '-palladium(II) chloride complexes, one '-palladium(II) acetate complex of 2,4--azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride '-complexes of 2,4--azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A ' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4--disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.
制备了七种2,4-氮杂环丁烷的二氯化钯（II）配合物、一种2,4-氮杂环丁烷的醋酸钯（II）配合物，并通过单晶X射线衍射进行分析。制备了两种2,4-氮杂环丁烷的二氯化铂（II）配合物，并通过单晶X射线衍射进行分析。进行了计算分析并测定了%Vbur。通过将钯（0）氧化加成到邻溴2,4-二取代氮杂环丁烷制备了一种金属环配合物，其晶体结构显示出金属-配体取向略有锥化。
