Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan.
Chem Commun (Camb). 2018 Jul 19;54(59):8226-8228. doi: 10.1039/c8cc04335c.
Preparation of an accurate assembly of phthalocyanines is rather difficult because of the high aggregation property of phthalocyanines. In this study, a novel discrete phthalocyanine dimer was prepared in which the relative configuration of each component was tightly and accurately fixed in an H-aggregate form by a rigid U-shaped linker. Electrochemical measurements showed that there were strong intramolecular electronic interactions between the two phthalocyanines.
由于酞菁的高聚集性质，准确组装酞菁非常困难。在这项研究中，通过刚性 U 型连接体，以 H 聚集形式将各组成部分的相对构型紧密且准确地固定，制备了一种新型离散酞菁二聚体。电化学测量表明，两个酞菁之间存在强烈的分子内电子相互作用。
