Boreskov Institute of Catalysis, Novosibirsk, 630090, Russian Federation; Novosibirsk State University, Novosibirsk, 630090, Russian Federation.
Boreskov Institute of Catalysis, Novosibirsk, 630090, Russian Federation; Novosibirsk State University, Novosibirsk, 630090, Russian Federation.
J Hazard Mater. 2018 Sep 15;358:302-309. doi: 10.1016/j.jhazmat.2018.06.035. Epub 2018 Jun 30.
The TiO and composite TiO/zeolite catalysts were investigated in the photocatalytic oxidation of model volatile organic compounds. The photocatalytic experiments were performed in a batch reactor using an FTIR in situ method for the detailed analysis of the reaction components in the gas phase. The kinetic data for the TiO and composite TiO/zeolite photocatalysts were compared. A focus on the analysis of the total hazard of gas mixture during the process by using the total hazard index, which includes the contribution of all the gas-phase components, was made. The effect of composite TiO/zeolite photocatalyst on the total hazard during the photocatalytic oxidation of different VOCs is studied and discussed. The composite TiO/zeolite photocatalyst allows for suppressing the secondary pollution with harmful intermediates formed during the process that increases the efficiency of air purification compared to TiO alone.
研究了 TiO 和复合 TiO/沸石催化剂在模型挥发性有机化合物的光催化氧化中的作用。使用 FTIR 原位方法在间歇式反应器中进行光催化实验,以详细分析气相中的反应成分。比较了 TiO 和复合 TiO/沸石光催化剂的动力学数据。通过使用总危害指数(包括所有气相成分的贡献),重点分析了过程中混合气体的总危害。研究并讨论了复合 TiO/沸石光催化剂对不同 VOCs 的光催化氧化过程中总危害的影响。与单独的 TiO 相比,复合 TiO/沸石光催化剂可以抑制过程中形成的有害中间体引起的二次污染,从而提高空气净化效率。