使用威尔金森催化剂进行二甲基胺硼烷的机械化学脱氢偶联和加氢反应。
Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst.
机构信息
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany.
出版信息
Chem Commun (Camb). 2018 Jul 24;54(60):8355-8358. doi: 10.1039/c8cc04487b.
PMID:29993055
Abstract
Mechanochemistry enabled the selective synthesis of the recherché orange polymorph of Wilkinson's catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NH·BH3 in a ball mill. The in situ-generated hydrogen (H2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.
摘要
机械化学实现了威尔金森催化剂[RhCl(PPh3)3]稀有橙色多晶型物的选择性合成。机械化学制备的 Rh 配合物在球磨机中催化 Me2NH·BH3 的无溶剂脱氢反应。原位生成的氢气（H2）可通过球磨用于 Rh 催化的加氢反应。
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