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硫属化合物或硫基锂离子电池。

Li S- or S-Based Lithium-Ion Batteries.

机构信息

Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 Cass Ave, Lemont, IL, 60439, USA.

Department of Chemical Engineering, Waterloo Institute of Nanotechnology, University of Waterloo, 200 University Ave West, Waterloo, ON, N2L 3G1, Canada.

出版信息

Adv Mater. 2018 Nov;30(48):e1801190. doi: 10.1002/adma.201801190. Epub 2018 Jul 15.

Abstract

While members of the Li-S battery research community are becoming more conscious of the practical testing parameters, the widespread commercialization of S-based batteries is still far from realization. Particularly, the metallic Li used as the anode poses potential safety and cycle stability concerns. Alternatively, other S-battery configurations without a Li anode, i.e., lithium-ion, Li S, or S batteries, do not suffer from the same safety concerns and can possibly serve as better methods to bring room-temperature S-based battery technologies to industry. However, whether Li S or S will be used as the initiating cathode material remains unclear as each offers their own unique advantages and disadvantages. Here, both S and Li S as cathodes are briefly discussed and the key benefits of Li S are highlighted.

摘要

虽然 Li-S 电池研究界的成员越来越意识到实际测试参数的重要性,但 S 基电池的广泛商业化仍远未实现。特别是,作为阳极的金属 Li 存在潜在的安全和循环稳定性问题。相比之下,其他不含 Li 阳极的 S 电池配置,即锂离子、Li S 或 S 电池,不存在同样的安全问题,并且可能作为将室温 S 基电池技术推向工业界的更好方法。然而,Li S 或 S 将被用作起始阴极材料尚不清楚,因为它们各自具有独特的优缺点。在这里,简要讨论了 S 和 Li S 作为阴极,并强调了 Li S 的关键优势。

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