含二氢磷酸的双核双组装体，展示了对四氟硼酸阴离子的磷酸反应性。
Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion.
机构信息
Department of Chemical Sciences, School of Applied Sciences, University of Huddersfield, Huddersfield HD1 3DH, UK.
出版信息
Chem Commun (Camb). 2018 Aug 14;54(66):9159-9162. doi: 10.1039/c8cc04900a.
PMID:30062337
Abstract
The ligands L1 and L2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu2L2(H2PO4)]3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu3(L1)3(O3POBF3)]3+ and [Cu2(L2)2(O2P(OBF3)2)]+.
摘要
配体 L1 和 L2 均与 Cu(ii) 形成双核配合物，这些配合物与磷酸二氢盐反应，使阴离子结合在配合物中（例如 [Cu2L2(H2PO4)]3+）。然而，在四氟硼酸根阴离子存在下，磷酸根与阴离子反应生成 [Cu3(L1)3(O3POBF3)]3+和 [Cu2(L2)2(O2P(OBF3)2)]+。
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