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评估新型管道材料中铅的释放潜力。

Evaluation of lead release potential of new premise plumbing materials.

机构信息

Graduate Institute of Environmental Engineering, National Taiwan University, Taipei, 10617, Taiwan.

Department of Environmental Engineering and Management, Chaoyang University of Technology, No. 168, Jifeng E. Rd, Wufeng District, Taichung, 41349, Taiwan.

出版信息

Environ Sci Pollut Res Int. 2018 Oct;25(28):27971-27981. doi: 10.1007/s11356-018-2816-2. Epub 2018 Jul 31.

Abstract

Premise plumbing materials such as pipes, valves, fittings, and faucets are made of various materials, including plastic, stainless steel, copper, and brass/bronze. Although lead pipe has been banned for its use in drinking water supply by most countries in the 1980s, lead is still commonly used as an additive in many plumbing materials for its flexibility and malleability. Certified leaching tests for plumbing materials are usually conducted using relatively mild solutions over short periods which may not reveal the true risk of lead exposure when these materials are used. The objective of this study is to investigate the extents of lead release from commonly used premise plumbing materials into drinking water. The maximum lead leaching potential for pluming material was operationally determined using high strength acidic EDTA solutions (pH 4, EDTA = 100 mg/L) for a stagnation time of 3 days for a total period of up to 1 month. Lead leaching from each plumbing material was also evaluated using reconstituted tap water. Brass- and bronze-based plumbing materials were found to release dangerous levels of lead. Surface lead weight percentage obtained using SEM-EDX and lead weight percentages of the material body obtained using strong acid digestion were found to positively correlate with lead release. A re-examination of the appropriateness of current certified leaching tests and a more stringent regulation on the use of lead as an additive for plumbing materials should be considered.

摘要

前提管道材料,如管道、阀门、管件和水龙头,由各种材料制成,包括塑料、不锈钢、铜和黄铜/青铜。尽管大多数国家在 20 世纪 80 年代已经禁止将铅用于饮用水供应,但由于其柔韧性和延展性,铅仍被广泛用作许多管道材料的添加剂。用于管道材料的认证浸出测试通常使用相对温和的溶液在短时间内进行,当这些材料被使用时,可能无法揭示铅暴露的真实风险。本研究的目的是调查饮用水中常用的前提管道材料中铅的释放程度。使用高强度酸性 EDTA 溶液(pH 值为 4,EDTA=100mg/L)在停滞时间为 3 天的情况下,操作确定管道材料的最大铅浸出潜力,总时间长达 1 个月。还使用再​​制自来水评估了每种管道材料的铅浸出情况。发现黄铜和青铜基管道材料释放出危险水平的铅。使用 SEM-EDX 获得的表面铅重量百分比和使用强酸消化获得的材料体的铅重量百分比与铅释放呈正相关。应重新审查当前认证浸出测试的适当性,并应考虑对铅作为管道材料添加剂的使用进行更严格的监管。

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