“原位”生成的全氟硫酮的 Diels-Alder 反应。
Diels-Alder reactions of "in situ" generated perfluorinated thioketones.
机构信息
Chemours Co., Fluoroproducts, 200 Powder Mill Rd., Experimental Station E262/339, Wilmington, DE 19803, USA.
出版信息
Chem Commun (Camb). 2018 Aug 16;54(67):9298-9300. doi: 10.1039/c8cc05075a.
PMID:30067262
Abstract
A simple and general procedure for the preparation of Diels-Alder adducts of perfluorinated thioketones and various dienes is reported. The corresponding Diels-Alder adducts were prepared in 30-78% yield under mild conditions via a reaction of a mixture of fluoroolefins, sulfur, diene and CsF as a catalyst.
摘要
本文报道了一种简单通用的制备全氟硫酮与各种二烯 Diels-Alder 加合物的方法。在温和条件下，通过氟烯烃、硫、二烯和 CsF 作为催化剂的混合物反应，以 30-78%的产率得到相应的 Diels-Alder 加合物。
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