Syntheses, structures and magnetic properties of macrocyclic Schiff base-supported homodinuclear lanthanide complexes.

Five new homodinuclear lanthanide complexes with the general formula [(acac)4Ln2(L)] (Ln3+ = Dy3+ (1), Tb3+ (2), Ho3+ (3), Er3+ (4), and Gd (5)) were synthesized by one-pot [2 + 2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane in the presence of various lanthanide acetylacetonates. The eight-coordinate Ln(iii) centre adopts a slightly distorted square antiprism geometry with D4d symmetry. Theoretical analysis and magnetic measurements reveal that the corresponding Dy complex 1 exhibits slow magnetic relaxation behavior, characteristic of a typical SMM with the intramolecular ferromagnetic Dy3+Dy3+ interaction.