He Xing, Cao Yu, Lang Xian-Dong, Wang Ning, He Liang-Nian
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin, 300071, P. R. China.
ChemSusChem. 2018 Oct 11;11(19):3382-3387. doi: 10.1002/cssc.201801621. Epub 2018 Aug 29.
Efficient conversion of CO into fuels and chemicals with solar energy would be promising, but also faces great challenge. In this context, we describe the photoreductive functionalization of CO to construct new C-C, C-N, and C-O bonds through the respective Pd-catalyzed Suzuki carbonylation, aminocarbonylation, and alkoxycarbonylation of aryl iodides with CO in situ generated through the photoreduction of CO . This protocol opens up an alternative avenue for CO utilization by harnessing solar energy.
利用太阳能将一氧化碳高效转化为燃料和化学品具有广阔前景，但也面临巨大挑战。在此背景下，我们描述了一氧化碳的光还原功能化，即通过芳基碘化物与原位光还原一氧化碳生成的一氧化碳分别进行钯催化的铃木羰基化、氨基羰基化和烷氧基羰基化反应，构建新的碳 - 碳、碳 - 氮和碳 - 氧键。该方案为利用太阳能实现一氧化碳的利用开辟了一条新途径。
