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Stereoselectivity in the binding of the bis(acetylacetonato)(nitro)cobalt(III) moiety to purines and pyrimidines and their nucleosides, and evaluation of the role of interligand interactions in stereoselectivity, and the molecular and crystal structure of the bis(acetylacetonato)(nitro)(deoxyadenosine)cobalt(III) complex.

作者信息

Sorrell T, Epps L A, Kistenmacher T J, Marzilli L G

出版信息

J Am Chem Soc. 1977 Mar 30;99(7):2173-9. doi: 10.1021/ja00449a025.

DOI:10.1021/ja00449a025
PMID:301147
Abstract
摘要

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Stereoselectivity in the binding of the bis(acetylacetonato)(nitro)cobalt(III) moiety to purines and pyrimidines and their nucleosides, and evaluation of the role of interligand interactions in stereoselectivity, and the molecular and crystal structure of the bis(acetylacetonato)(nitro)(deoxyadenosine)cobalt(III) complex.双（乙酰丙酮基）（硝基）钴（III）部分与嘌呤、嘧啶及其核苷结合中的立体选择性，配体间相互作用在立体选择性中的作用评估，以及双（乙酰丙酮基）（硝基）（脱氧腺苷）钴（III）配合物的分子和晶体结构。
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