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一种带有硫醚侧臂的共价有机框架,用于从超低浓度水溶液中选择性地检测和回收金。

A covalent organic framework bearing thioether pendant arms for selective detection and recovery of Au from ultra-low concentration aqueous solution.

机构信息

College of Materials Science and Engineering, Fuzhou University, Minhou, Fujian 350108, China.

Key Laboratory of Eco-materials Advanced Technology, Fuzhou University, Fuzhou, Fujian 350108, China.

出版信息

Chem Commun (Camb). 2018 Sep 14;54(71):9977-9980. doi: 10.1039/c8cc05369c. Epub 2018 Aug 20.

Abstract

A fluorescent covalent organic framework (COF), featuring precise distribution of thioether pendant arms inside the cavity, was designed. The thioether-functionalized COF exhibits selective sensing and capture of Au ions at ultra-trace levels in water with high sensitivity, selectivity and adsorption capacity, which makes it an excellent candidate for selective detection and recovery of Au.

摘要

一种荧光共价有机框架(COF),具有腔内硫醚侧臂的精确分布,被设计出来。这种硫醚功能化的 COF 在水中对痕量金离子表现出高灵敏度、选择性和吸附容量的选择性传感和捕获,使其成为选择性检测和回收金的优秀候选材料。

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