Department Química Física i Inorgànica, University Rovira i Virgili, Tarragona, Spain.
Chem Commun (Camb). 2018 Sep 6;54(72):10104-10107. doi: 10.1039/c8cc06153j.
1,2,3-Triborated compounds can be prepared by simple nucleophilic borylation of 1,3-dienes, without the assistance of metal catalysts. Selective functionalisation of the internal C-B bond of the 1,2,3-triborated compounds, through cross-coupling with aryl iodides, highlights the powerful methodology toward polyfunctionalisation.
1,2,3-三硼化合物可通过 1,3-二烯的简单亲核硼化作用制备，无需金属催化剂的协助。通过与芳基碘化物的交叉偶联，对 1,2,3-三硼化合物的内部 C-B 键进行选择性官能化，突出了该方法在多官能化方面的强大。
