Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, Iran.
Chem Commun (Camb). 2018 Sep 13;54(74):10427-10430. doi: 10.1039/c8cc06334f.
The first example of hydrogen evolution reactivity (HER) of lanthanide-functionalized Keggin-based polyoxotungstates under photochemical and electrochemical conditions is reported. The HER activity under homogeneous, visible light-driven conditions and under heterogeneous, electrochemical conditions depends on the type of lanthanide functionalization, so that a new class of model HER catalysts for systematic reactivity studies is now accessible.
首例镧系元素功能化 Keggin 型多钨酸盐在光化学和电化学条件下的析氢反应（HER）活性被报道。在均相、可见光驱动条件和多相、电化学条件下的 HER 活性取决于镧系元素功能化的类型，因此现在可以获得用于系统反应性研究的新型模型 HER 催化剂。
