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室温下SDBS-WO薄膜的光电气敏特性检测

Optical-Electricity Gas-Sensing Property Detection of SDBS-WO Film at Room Temperature.

作者信息

Zhang Yuan, Wang Jiaming, Abudukeremu Hannikezi, Nizamidin Patima, Abliz Shawket, Yimit Abliz

机构信息

College of Chemistry and Chemical Engineering, Xinjiang University.

出版信息

Anal Sci. 2018 Dec 10;34(12):1385-1391. doi: 10.2116/analsci.18P226. Epub 2018 Aug 31.

Abstract

In this work, sodium dodecyl benzene sulfonate (SDBS) was used as a dispersing agent; a WO nanoparticle suspension was used as a sensing material. The SDBS-WO thin film/Sn-doped glass optical waveguide sensor element was prepared by spin coating. The sensing material was characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and field-emission scanning electron microscopy (FESEM). The gas-sensing characteristics of the fabricated sensors were studied at room temperature for various gases. The experimental results indicate that the sensor exhibited a high selective response toward SO and HS and a low detection limit of 10 ppb to SO and HS. The response/recovery times for SO and HS were 2/23 and 2/18 s. However, during an electrochemical gas-sensing performance test of the SDBS-WO film at room temperature, the results indicated that the trend of the variation in resistance was consistent with the variation in the output light.

摘要

在本工作中,使用十二烷基苯磺酸钠(SDBS)作为分散剂;使用WO纳米颗粒悬浮液作为传感材料。通过旋涂制备了SDBS-WO薄膜/掺锡玻璃光波导传感器元件。采用傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)和场发射扫描电子显微镜(FESEM)对传感材料进行了表征。在室温下研究了所制备传感器对各种气体的气敏特性。实验结果表明,该传感器对SO和HS表现出高选择性响应,对SO和HS的检测下限低至10 ppb。对SO和HS的响应/恢复时间分别为2/23和2/18 s。然而,在室温下对SDBS-WO薄膜进行电化学气敏性能测试时,结果表明电阻变化趋势与输出光的变化一致。

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