Leibniz-Institut für Katalyse an der Universität Rostock e. V. , Albert-Einstein-Straße 29a , 18059 Rostock , Germany.
Org Lett. 2018 Sep 21;20(18):5938-5941. doi: 10.1021/acs.orglett.8b02631. Epub 2018 Sep 4.
A procedure on palladium-catalyzed decarboxylative alkoxycarbonylation of carbonates for the synthesis of aryl 2-arylacetates has been developed. A broad range of aryl 2-arylacetates were obtained in good yields under mild conditions under a carbon monoxide atmosphere. Interestingly, other alcohols can be added as nucleophiles as well, and the corresponding esters were also obtained in good yields.
发展了一种钯催化的碳酸酯脱羧基烷氧基羰基化反应合成芳基 2-芳基乙酸酯的方法。在一氧化碳气氛下，温和条件下，该方法能以良好的收率得到广泛的芳基 2-芳基乙酸酯。有趣的是，其他醇也可以作为亲核试剂添加，并且也能以良好的收率得到相应的酯。
