无热无光——室温制备硫聚合物的未来一片光明。
No Heat, No Light-The Future of Sulfur Polymers Prepared at Room Temperature Is Bright.
作者信息
He Lirong, Zhao Hui, Theato Patrick
机构信息
Institute for Technical and Macromolecular Chemistry, University of Hamburg, Bundesstrasse 45, 20146, Hamburg, Germany.
Institute of Fundamental Science and Frontiers, University of Electronic Science and Technology of China, Chengdu, 610054, China.
出版信息
Angew Chem Int Ed Engl. 2018 Oct 1;57(40):13012-13014. doi: 10.1002/anie.201807005. Epub 2018 Sep 5.
PMID:30183117
Abstract
Follow the yellow brick road: Functional polymers can be prepared directly at room temperature from elemental sulfur by the Willgerodt-Kindler reaction. This method opens a new synthetic door for the synthesis and application of polythioamides and polythioureas.
摘要
沿着黄砖路前行
通过威尔格罗德特-金德勒反应，可以在室温下直接由元素硫制备功能聚合物。该方法为聚硫酰胺和聚硫脲的合成及应用打开了一扇新的合成大门。
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