Sullivan Kevin P, Yin Qiushi, Collins-Wildman Daniel L, Tao Meilin, Geletii Yurii V, Musaev Djamaladdin G, Lian Tianquan, Hill Craig L
Department of Chemistry, Emory University, Atlanta, GA, United States.
Emerson Center for Scientific Computation, Emory University, Atlanta, GA, United States.
Front Chem. 2018 Aug 21;6:365. doi: 10.3389/fchem.2018.00365. eCollection 2018.
Polyoxometalate (POM)-based materials of current interest are summarized, and specific types of POM-containing systems are described in which material facilitates multiple complex interactions or catalytic processes. We specifically highlight POM-containing multi-hydrogen-bonding polymers that form gels upon exposure to select organic liquids and simultaneously catalyze hydrolytic or oxidative decontamination, as well as water oxidation catalysts (WOCs) that can be interfaced with light-absorbing photoelectrode materials for photoelectrocatalytic water splitting.
本文总结了当前受到关注的基于多金属氧酸盐（POM）的材料，并描述了特定类型的含POM体系，其中材料促进了多种复杂的相互作用或催化过程。我们特别强调了含POM的多氢键聚合物，它们在暴露于特定有机液体时形成凝胶，同时催化水解或氧化去污，以及可与吸光光电极材料连接用于光电催化水分解的水氧化催化剂（WOC）。
