Meng Fan-Hao, Qin Min, Liang Shuai-Xi, Xie Pin-Hua, Xia Hui-Hui, Duan Jun, Fang Wu, Tang Ke, Li Ang, Wei Zhen, Wang Feng
Key Laboratory of Environment Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.
University of Science and Technology of China, Hefei 230026, China.
Huan Jing Ke Xue. 2018 Sep 8;39(9):4060-4069. doi: 10.13227/j.hjkx.201712250.
In order to study levels of BTX near a main road in Hefei in March 2016, benzene, toluene, -xylene, and -xylene (BTX) and conventional pollutants (such as NO and SO) in the atmosphere were monitored through a home-made differential optical absorption spectroscopy (DOAS) system. Results showed that average concentrations of benzene, toluene, -xylene, and -xylene were 21.7, 63.6, 33.9, and 98.7 μg·m, respectively. Compared with other cities both in China and elsewhere, benzene and toluene pollution can be considered to be of medium level, while xylene pollution is serious. Wind direction, T/B ratio, and correlation with CO were also analyzed, together with BTX sources. Result showed that the T/B ratio was 0.8-4.5, with correlation coefficients of benzene, toluene, and CO of 0.55 and 0.34, respectively. These values indicate that benzene and toluene are mainly derived from automotive emissions, also affected by surrounding industrial parks. Xylene is mainly derived from a coating industrial park north of the observation site. It was shown that high night-time concentrations of benzene and toulene could be due to industrial emissions from the industrial parks around the observation site. The ozone formation potential is in the order of -xylene > -xylene > toulene > benzene at the observation site. The ozone formation potential of xylene accounted for 85% of total ozone formation potential, indicating that emissions from surrounding industrial parks contribute greatly to ozone formation in the area.
为研究2016年3月合肥市某主干道附近的苯系物(BTX)水平,通过自制的差分光学吸收光谱(DOAS)系统对大气中的苯、甲苯、间二甲苯、对二甲苯(BTX)及常规污染物(如NO和SO)进行了监测。结果表明,苯、甲苯、间二甲苯、对二甲苯的平均浓度分别为21.7、63.6、33.9和98.7 μg·m。与中国其他城市及其他地区相比,苯和甲苯污染可认为处于中等水平,而二甲苯污染严重。还分析了风向、T/B比以及与CO的相关性,并探讨了BTX的来源。结果表明,T/B比为0.8 - 4.5,苯、甲苯与CO的相关系数分别为0.55和0.34。这些数值表明苯和甲苯主要源自汽车尾气排放,同时也受到周边工业园区的影响。二甲苯主要源自观测点以北的一个涂料工业园区。结果显示,夜间苯和甲苯的高浓度可能归因于观测点周边工业园区的工业排放。在观测点,臭氧生成潜势大小顺序为:对二甲苯 > 间二甲苯 > 甲苯 > 苯。二甲苯的臭氧生成潜势占总臭氧生成潜势的85%,表明周边工业园区的排放对该地区臭氧生成有很大贡献。