钯（I）促进的硼和锑亲核试剂的氧化交叉偶联。
Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I).
机构信息
School of Chemistry , Monash University , Clayton 3800 , Victoria , Australia.
Department of Chemistry , University of Warwick , Gibbet Hill Road , Coventry CV4 7AL , U.K.
出版信息
Org Lett. 2018 Sep 21;20(18):5537-5540. doi: 10.1021/acs.orglett.8b01989. Epub 2018 Sep 7.
PMID:30192552
Abstract
The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.
摘要
本文报道了一种可分离的、单体钯（I）配合物作为催化剂，用于芳基-锑和芳基-硼亲核试剂的氧化交叉偶联反应。该反应对多种底物具有耐受性，交叉偶联产物的选择性大于 20:1。该策略为实现亲核试剂的选择性交叉偶联提供了一种新方法。
Zotero 插件