手性卤素和硫属元素键受体用于识别水相中的立体和几何二羧酸异构体。
Chiral halogen and chalcogen bonding receptors for discrimination of stereo- and geometric dicarboxylate isomers in aqueous media.
机构信息
Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK.
出版信息
Chem Commun (Camb). 2018 Sep 25;54(77):10851-10854. doi: 10.1039/c8cc06400h.
PMID:30199082
Abstract
Novel chiral halogen and chalcogen bonding receptors exhibit different selectivities for stereo- and geometric dicarboxylate isomers compared to a hydrogen bonding analogue. The unique geometric and electronic properties of the chalcogen bonding receptor facilitate the diagnostic fluorescence sensing of geometric dicarboxylate isomer guest species.
摘要
新型手性卤键和硫属键受体与氢键类似物相比，对立体和几何二羧酸异构体表现出不同的选择性。硫属键受体独特的几何和电子性质促进了几何二羧酸异构体客体物种的荧光诊断传感。
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