College of Computer Science and Software Engineering , Shenzhen University , Shenzhen , 518060 , China.
Department of Physics , The Hong Kong University of Science and Technology , Clear Water Bay, Kowloon , Hong Kong 999077 , China.
ACS Appl Mater Interfaces. 2018 Oct 10;10(40):34418-34426. doi: 10.1021/acsami.8b05950. Epub 2018 Sep 25.
In this work, we report the application of the aggregation-induced emission luminogens (AIEgens) as color converters for visible light communication (VLC). In the form of pure solid powder, the AIEgens studied herein have demonstrated blue-to-red full-color emissions, large -6 dB electrical modulation bandwidths up to 279 MHz (∼56× that of commercial phosphor), and most of them can achieve high data rates of 428-493 Mbps (up to ∼49× that of commercial phosphor) at a maximum bit error rate of 3.8 × 10 using on-off keying. Their data communication performances strongly suggest that AIEgens are very promising candidates as color converters for VLC applications, together with their unique AIE properties that will benefit usage in high concentration. Based on the comprehensive experimental results, we further propose some insights into improving data rate of the color converter in VLC: the data rate limit is influenced by modulation bandwidth and signal-noise ratio (SNR). We have experimentally proved that the -6 dB electrical modulation bandwidth f can be estimated from the effective lifetime τ of the color converter with the theoretical prediction of [Formula: see text] within experimental uncertainties, while theoretically derived that the SNR is proportional to its PL quantum efficiency. These observations and implications are very profound for exploring materials as color converters and improve the data transmission performance in VLC.
在这项工作中,我们报告了聚集诱导发光体(AIEgens)在可见光通信(VLC)中作为颜色转换器的应用。以纯固态粉末的形式,我们所研究的 AIEgens 表现出蓝到红的全色发射,高达 279 MHz 的大-6 dB 电调制带宽(约为商业荧光粉的 56 倍),其中大部分可以实现高达 428-493 Mbps 的高速率(约为商业荧光粉的 49 倍),最大误码率为 3.8×10 使用开关键控。它们的数据通信性能强烈表明,AIEgens 是 VLC 应用中作为颜色转换器的很有前途的候选材料,再加上它们独特的 AIE 性质,这将有利于在高浓度下使用。基于综合实验结果,我们进一步提出了一些关于提高 VLC 中颜色转换器数据速率的见解:数据速率限制受调制带宽和信号噪声比(SNR)的影响。我们已经通过实验证明,颜色转换器的-6 dB 电调制带宽 f 可以从其有效寿命 τ 用公式 [Formula: see text] 进行理论预测来估计,而 SNR 则与它的 PL 量子效率成正比。这些观察和启示对于探索颜色转换器材料和提高 VLC 中的数据传输性能非常重要。