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大豆壳和咖啡渣高温及低温热解产生的生物炭表征:用于聚合物复合材料应用

Characterization of biocarbon generated by high- and low-temperature pyrolysis of soy hulls and coffee chaff: for polymer composite applications.

作者信息

Quosai Peter, Anstey Andrew, Mohanty Amar K, Misra Manjusri

机构信息

Bioproduct Development and Discovery Centre, Department of Plant Agriculture, University of Guelph, Guelph, Canada.

School of Engineering, University of Guelph, Guelph, Canada.

出版信息

R Soc Open Sci. 2018 Aug 22;5(8):171970. doi: 10.1098/rsos.171970. eCollection 2018 Aug.

Abstract

The physical properties of biocarbon vary widely with the biomass used, and the temperature and duration of pyrolysis. This study identifies the effects of feedstock characteristics and pyrolysis conditions on the production of biocarbon and the corresponding properties for industrial applications. For coffee chaff and soy hulls, ash content and carbon content increased with pyrolysis temperature and duration. Ash content increased thermal conductivity and specific heat, and decreased electrical conductivity. Change in surface area with pyrolysis conditions was dependent on type of feedstock. Increased surface area corresponded with increased thermal and electrical conductivity. Increased carbon content corresponded with increased graphitization and thermal stability and decreased surface functionality. Properties of soy hull biocarbons were found to be similar to the properties of other biocarbons with industrial applications such as incorporation into polymer composites.

摘要

生物炭的物理性质会因所用生物质、热解温度和持续时间的不同而有很大差异。本研究确定了原料特性和热解条件对生物炭产量及工业应用中相应性能的影响。对于咖啡渣和大豆壳,灰分含量和碳含量随热解温度和持续时间的增加而增加。灰分含量增加了热导率和比热容,并降低了电导率。表面积随热解条件的变化取决于原料类型。表面积增加与热导率和电导率增加相对应。碳含量增加与石墨化程度提高、热稳定性增强以及表面官能团减少相对应。研究发现,大豆壳生物炭的性能与其他用于工业应用(如掺入聚合物复合材料)的生物炭性能相似。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/260c/6124110/365f47aac742/rsos171970-g1.jpg

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