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用光声红外光谱法评估大气氮损失:聚合物包裹尿素。

Assessing atmospheric nitrogen losses with photoacoustic infrared spectroscopy: Polymer coated urea.

机构信息

Department of Plant and Wildlife Sciences, Brigham Young University, Provo, UT, United States of America.

出版信息

PLoS One. 2018 Sep 18;13(9):e0204090. doi: 10.1371/journal.pone.0204090. eCollection 2018.

DOI:10.1371/journal.pone.0204090
PMID:30226891
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6143244/
Abstract

Although N is beneficial and essential for life, it is also a common atmospheric pollutant as nitrous oxide (N2O) and ammonia (NH3)-contributed largely from N fertilization. Polymer-coated urea (PCU) fertilizer is a promising controlled release fertilizer that provides improved N-release timing. Glasshouse studies were conducted to compare N2O and NH3 emissions from PCU and uncoated urea to an untreated control utilizing a non-static, non-flow-through chamber in conjunction with photoacoustic infrared spectroscopy (PAIRS) for gas collection and analysis. Three short-term 20-Day Studies with sand, sandy loam, and loam soils and a full-term 45-Day Study with loam soil were completed. Volatilization of NH3 was reduced by 72% and 22% in the sandy loam and loam soils, respectively, in two of the short-term studies and by 14% in the loam in the full-term study. Evolution of N2O was reduced by 42% and 63% in the sandy loam and loam soils of the short-term studies and by 99% in the loam soil of the full-term study. No differences were observed in the sand soil. Overall, PCU decreased gaseous losses of N following fertilization while providing a steady supply of N to the plant. Higher temporal resolution was observed with the PAIRS instrumentation as compared to what is typically reported and, as such, we recommend PAIRS analysis as a viable method for studying N gas emissions.

摘要

尽管氮是生命所必需的有益元素,但它也是一种常见的大气污染物,如氧化亚氮(N2O)和氨(NH3)——主要来自氮肥。聚合物包膜尿素(PCU)是一种很有前途的控释肥料,它提供了改善的氮释放时间。利用非静态、非流通室结合光声红外光谱(PAIRS)进行气体收集和分析,在温室中进行了比较 PCU 和未包膜尿素与未处理对照之间 N2O 和 NH3 排放的研究。完成了三个短期 20 天的沙质壤土、壤土和壤土土壤研究和一个长期 45 天的壤土土壤研究。在两个短期研究中,氨的挥发分别减少了 72%和 22%,在短期研究中,在壤土中减少了 14%。在短期研究中,N2O 的演化分别减少了 42%和 63%,在长期研究中,在壤土中减少了 99%。在沙土中没有观察到差异。总的来说,PCU 减少了施肥后气态氮的损失,同时为植物提供了稳定的氮供应。与通常报道的相比,PAIRS 仪器具有更高的时间分辨率,因此我们建议将 PAIRS 分析作为研究 N 气体排放的可行方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/2b7248e3a5b6/pone.0204090.g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/eae1dfe5796a/pone.0204090.g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/d1aac494bd71/pone.0204090.g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/395d1c85b4bb/pone.0204090.g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/2b7248e3a5b6/pone.0204090.g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/eae1dfe5796a/pone.0204090.g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/d1aac494bd71/pone.0204090.g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/395d1c85b4bb/pone.0204090.g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d415/6143244/2b7248e3a5b6/pone.0204090.g004.jpg

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Nitrogen source effects on nitrous oxide emissions from irrigated no-till corn.氮源对免耕灌溉玉米一氧化二氮排放的影响。
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Banding of urea increased ammonia volatilization in a dry acidic soil.在干燥的酸性土壤中,尿素包膜会增加氨的挥发。
J Environ Qual. 2009 May 20;38(4):1383-90. doi: 10.2134/jeq2008.0295. Print 2009 Jul-Aug.
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Ammonia in the environment: from ancient times to the present.环境中的氨:从古代到现代。
Environ Pollut. 2008 Dec;156(3):583-604. doi: 10.1016/j.envpol.2008.03.013. Epub 2008 May 22.
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