基于环糊精的[3]轮烷交联荧光聚合物：利用尺寸互补性进行合成与去交联
Cyclodextrin-Based [3]Rotaxane-Crosslinked Fluorescent Polymer: Synthesis and De-Crosslinking Using Size Complementarity.
作者信息
Akae Yosuke, Sogawa Hiromitsu, Takata Toshikazu
机构信息
Department of Chemical Science and Engineering, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo, 152-8552, Japan.
出版信息
Angew Chem Int Ed Engl. 2018 Nov 5;57(45):14832-14836. doi: 10.1002/anie.201809171. Epub 2018 Oct 15.
Vinyl-group-substituted, α-cyclodextrin-based, size-complementary [3]rotaxanes were synthesized as crosslinkers for rotaxane-crosslinked poly(methyl methacrylate) (RCP) by radical polymerization. The size complementarity of the crosslinkers made it possible to de-crosslink the RCP by heating, and the degree of decoupling was monitored by fluorescence intensity, depending on the state of the axle component of the rotaxane crosslink moiety.
乙烯基取代的、基于α-环糊精的尺寸互补[3]轮烷被合成为用于通过自由基聚合制备轮烷交联聚甲基丙烯酸甲酯（RCP）的交联剂。交联剂的尺寸互补性使得通过加热使RCP去交联成为可能，并且去偶联程度通过荧光强度进行监测，这取决于轮烷交联部分的轴组分的状态。
Zotero 插件