动态铜碘介孔配合物的发光蒸色性。
Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate.
机构信息
Laboratoire de Physique de la Matière Condensée (PMC), Ecole Polytechnique-CNRS, 91128, Palaiseau Cedex, France.
Laboratoire de Chimie Moléculaire (LCM), Ecole Polytechnique-CNRS, 91128, Palaiseau Cedex, France.
出版信息
Chemistry. 2018 Dec 17;24(71):18868-18872. doi: 10.1002/chem.201804377. Epub 2018 Nov 16.
A copper iodide complex coordinated by three phosphine ligands with the formula [Cu I (Ph PC (C H )C PPh ) ] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.
一种由三个膦配体配位的碘化亚铜配合物，化学式为[Cu I (Ph PC (C H )C PPh ) ]，具有溶剂化变色和蒸气变色发光性质。似乎发生了基于溶剂依赖性分子运动的机制。在暴露于四氢呋喃溶剂时观察到的高对比度响应使得该配合物成为化学传感器应用的有吸引力的候选物。
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