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在可见光照射下,负载在 BiMoO 纳米板上的 Pt 纳米粒子对烷基芳烃的选择有氧氧化。

Selective aerobic oxidation of alkyl aromatics on BiMoO nanoplates decorated with Pt nanoparticles under visible light irradiation.

机构信息

Key Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Materials Science and Engineering, and Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, China.

出版信息

Chem Commun (Camb). 2018 Oct 25;54(86):12194-12197. doi: 10.1039/c8cc06909c.

DOI:10.1039/c8cc06909c
PMID:30303206
Abstract

Pt/Bi2MoO6 nanoplates are efficient photocatalysts for the selective oxidation of saturated C-H bonds in alkyl aromatics under visible light illumination using O2 as an oxidant. This study opens a new window for direct C-H functionalization through the photocatalytic method based on cheap Bi2MoO6 semiconductor materials.

摘要

Pt/Bi2MoO6 纳米板是可见光照射下使用 O2 作为氧化剂将烷基芳烃中饱和 C-H 键选择性氧化的高效光催化剂。这项研究为基于廉价 Bi2MoO6 半导体材料的光催化方法实现直接 C-H 官能化开辟了新的窗口。

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