Jiangsu Collaborative Innovation Center for Photovoltaic Science and Engineering, Jiangsu Province Cultivation base for State Key Laboratory of Photovoltaic Science and Technology, Changzhou University, Changzhou 213164, P. R. China.
Nanoscale. 2018 Nov 7;10(41):19360-19366. doi: 10.1039/c8nr05897k. Epub 2018 Oct 11.
Self-healing conductive elastomers have emerged as a class of novel materials that are important for fabricating human-motion sensors, soft robots and healthcare monitoring systems. Herein, we report on a hydrogel of modified poly(γ-glutamic) acid polymer chains crosslinked by coordination complexes, which exhibits good stretchability (1375%), long-term stability (more than 40 days), and self-healing ability (99.0 ± 1.5% in 3 h). Furthermore, a "sandwich" structure composite was fabricated, which is composed of self-healing hydrogels and Au nanograin-decorated aligned multiwall carbon nanotube sheets. It possesses fast self-healing ability, a low stable electronic resistance of 10 ± 1 Ω sq, in the temperature range of -40-90 °C, the humidity range of 10-90%, and a stretching range up to 200%.
自修复导电弹性体作为一类新型材料已经出现，它们在制造人体运动传感器、软体机器人和医疗保健监测系统方面非常重要。在此，我们报告了一种由配位复合物交联的改性聚（γ-谷氨酸）聚合物链水凝胶，它具有良好的拉伸性（1375%）、长期稳定性（超过 40 天）和自修复能力（3 小时内达到 99.0±1.5%）。此外，还制备了一种“三明治”结构复合材料，它由自修复水凝胶和 Au 纳米颗粒修饰的取向多壁碳纳米管片组成。它具有快速的自修复能力，在-40-90°C 的温度范围、10-90%的湿度范围和高达 200%的拉伸范围内，稳定电子电阻低至 10±1Ωsq。
