Department of Electrical and Computer Engineering, National University of Singapore, Singapore, 117583, Republic of Singapore.
Institute of High Performance Computing, Singapore, Singapore, 138632, Republic of Singapore.
Adv Mater. 2018 Dec;30(50):e1804928. doi: 10.1002/adma.201804928. Epub 2018 Oct 11.
Black phosphorus (BP) has emerged as a promising candidate for next-generation electronics and optoelectronics among the 2D family materials due to its extraordinary electrical/optical/optoelectronic properties. Interestingly, BP shows strong anisotropic transport behavior because of its puckered honeycomb structure. Previous studies have demonstrated the thermal transport anisotropy of BP and theoretically attribute this to the anisotropy in both the phonon dispersion relation and the phonon relaxation time. However, the exact origin of such strong anisotropy lacks clarity and has yet to be proven experimentally. Here, the thermal transport anisotropy of BP nanoribbons is probed by an electron beam technique. Direct evidence is provided that the origin of this anisotropy is dominated by the anisotropic phonon group velocity, verified by Young's modulus measurements along different directions. It turns out that the ratio of the thermal conductivity between zigzag (ZZ) and armchair (AC) ribbons is almost same as that of the corresponding Young modulus values. The results from first-principles calculation are consistent with this experimental observation, where the anisotropic phonon group velocity between ZZ and AC is shown. These results provide fundamental insight into the anisotropic thermal transport in low-symmetry crystals.
黑磷(BP)由于其非凡的电学/光学/光电特性,在二维家族材料中脱颖而出,成为下一代电子学和光电子学的有前途的候选材料。有趣的是,BP 由于其褶皱的蜂窝状结构,表现出强烈的各向异性输运行为。先前的研究已经证明了 BP 的热输运各向异性,并从理论上归因于声子色散关系和声子弛豫时间的各向异性。然而,这种强各向异性的确切起源尚不清楚,有待实验证明。在这里,通过电子束技术研究了 BP 纳米带的热输运各向异性。提供了直接的证据,证明这种各向异性的起源主要由各向异性声子群速度决定,这通过沿不同方向的杨氏模量测量得到了验证。事实证明,锯齿形(ZZ)和扶手椅形(AC)纳米带之间热导率的比值几乎与相应杨氏模量值的比值相同。第一性原理计算的结果与这一实验观察一致,其中显示了 ZZ 和 AC 之间的各向异性声子群速度。这些结果为低对称晶体中各向异性热输运提供了基本的见解。