（）-3-[(2,6-二甲基苯基)重氮基]-7-甲基-1-吲唑的晶体结构
Crystal structure of ()-3-[(2,6-di-methyl-phen-yl)diazen-yl]-7-methyl-1-indazole.
作者信息
Yagi Shiomi, Haraguchi Tomoyuki, Akitsu Takashiro
机构信息
Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.
出版信息
Acta Crystallogr E Crystallogr Commun. 2018 Sep 14;74(Pt 10):1421-1423. doi: 10.1107/S2056989018012483. eCollection 2018 Oct 1.
The title azo compound, CHN, was synthesized from 2,6-di-methyl-aniline. The diazenyl group adopts a () conformation, with an N=N bond length of 1.265 (4) Å. The pyrazole ring is approximately planar. In the crystal, zigzag chains along the -axis direction with a (3) is graph-set motif are formed by N-H⋯N hydrogen bonds involving the pyrazole moiety.
标题偶氮化合物CHN由2,6-二甲基苯胺合成。重氮基采取()构象，N=N键长为1.265(4)Å。吡唑环近似平面。在晶体中，沿轴方向具有(3)图集模式的锯齿链由涉及吡唑部分的N-H⋯N氢键形成。
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