Naqvi Faria K, Faraz Mohd, Beg Saba, Khare Neeraj
Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India.
Department of Physic, Indian Institute of Technology Delhi, Delhi 110016, India.
ACS Omega. 2018 Sep 30;3(9):11300-11306. doi: 10.1021/acsomega.8b01012. Epub 2018 Sep 17.
Recently, BiVO as an electrolyte material has pulled in considerable consideration because of its remarkable novel applications. In this article, novel, dysprosium-doped ( = 0.2, 0.3, 0.4, and 0.5) BiVO (Dy/BVO) nanoparticles have been synthesized by sol-gel strategy. The photocatalyst Dy/BVO nanoparticles exhibit higher photocatalytic efficiency than BVO nanoparticles assessed by debasement of tetracycline drug under visible light illumination. Our work focuses on the phase transformation, conducting properties, and mechanisms of the Dy/BVO nanoparticles in relation to execute some methods of processing and manufacturing product in commercial applications. The characterization of Dy/BVO was performed by Fourier transform infrared, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray analysis, and UV-vis analysis. ac impedance spectroscopy was used to analyze the conducting behavior of synthesized nanoparticles in the temperature range 100-600 °C. The photocatalytic activity revealed that Dy/BVO remarkably enhanced the photocatalytic activity. This is the first report that Dy/BVO can destroy the drug effluent which is coming from the drug industry and also worried about the human health hazards.
最近,BiVO作为一种电解质材料因其显著的新颖应用而备受关注。在本文中,通过溶胶 - 凝胶法合成了新型的镝掺杂( = 0.2、0.3、0.4和0.5)BiVO(Dy/BVO)纳米颗粒。通过在可见光照射下四环素药物的降解评估,光催化剂Dy/BVO纳米颗粒比BVO纳米颗粒表现出更高的光催化效率。我们的工作重点在于Dy/BVO纳米颗粒的相变、导电性能以及相关机制,以实施商业应用中产品的一些加工和制造方法。通过傅里叶变换红外光谱、X射线衍射、扫描电子显微镜、能量色散X射线分析和紫外 - 可见分析对Dy/BVO进行了表征。使用交流阻抗谱分析了合成纳米颗粒在100 - 600°C温度范围内的导电行为。光催化活性表明Dy/BVO显著增强了光催化活性。这是关于Dy/BVO能够破坏来自制药行业且对人类健康有害的药物废水的首次报道。