Boosted Performance of Ir Species by Employing TiN as the Support toward Oxygen Evolution Reaction.

Reducing the noble-metal loading without sacrificing the catalytic performance of the oxygen evolution reaction (OER) catalysts is paramount yet highly challenging. Herein, IrO@Ir/TiN electrocatalysts employing TiN as the support have been developed and shown high efficiency toward OER. TiN is found not only to disperse the IrO@Ir nanoparticles effectively but also to exert the electronic modulation of Ir by downshifting its d-band center of 0.21 eV compared to pure IrO. Excitingly, TiN remarkably enhances the catalytic performance of Ir, where the overpotential to achieve the current density of 10 mA cm is only 265 mV for the IrO@Ir/TiN (60 wt %) catalyst. As a result, 71.7 wt % of the Ir metal can be saved to compare with the commercial Ir-black counterpart. Moreover, TiN can inhibit the aggregation and oxidative dissolution of Ir species, thereby enhancing the operational stability. The combined advantages of TiN open a new solution to reduce the anodic catalyst cost through boosting the catalytic activity and stability.