Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.
Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.
Carbohydr Polym. 2019 Jan 15;204:1-8. doi: 10.1016/j.carbpol.2018.09.082. Epub 2018 Oct 1.
Starch is an important class of macromolecules for human nutrition. However, its rapid digestibility leads to a high amount of glucose released into the blood and contributes to a high risk of obesity and type II diabetes. For these reasons, Heat-moisture treatment (HMT) of the starch was applied prior to complexation with linoleic acid to obtain a desired physicochemical properties while preserving its granular structure. The thermal properties, analyzed by DSC, implied that the HMT enhanced the formation of amylose-linoleic acid complexes, particularly when the complexation was succeeded at 70 °C. The viscosity behavior studied by RVA demonstrated a higher pasting temperature and lower peak viscosity due to less swelling. The granule-like structure remained after complexation at 70 °C for 30 min and followed by RVA to 85 °C. The combination of the HMT and linoleic acid addition improved the stability of the starch granules towards heating and shearing.
淀粉是人类营养的重要的一类高分子物质。然而,其快速的消化性导致大量的葡萄糖释放到血液中,增加了肥胖和 2 型糖尿病的风险。出于这些原因,在与亚油酸络合之前对淀粉进行湿热处理(HMT),以获得所需的物理化学性质,同时保持其颗粒结构。通过 DSC 分析的热性质表明,HMT 增强了直链淀粉-亚油酸复合物的形成,特别是当在 70°C 时成功络合时。通过 RVA 研究的粘度行为表明,由于溶胀度降低,糊化温度更高,峰值粘度更低。在 70°C 下络合 30 分钟并随后在 RVA 下加热至 85°C 后,颗粒状结构仍然存在。湿热处理与添加亚油酸的结合提高了淀粉颗粒对加热和剪切的稳定性。