金属催化的腈氧化物 1,3-偶极环加成反应。
Metal-catalyzed 1,3-dipolar cycloaddition reactions of nitrile oxides.
机构信息
Universidad Complutense, Facultad de Química, Departamento de Química Orgánica, Ciudad Universitaria, 28040, Madrid, Spain.
出版信息
Org Biomol Chem. 2018 Nov 14;16(44):8446-8461. doi: 10.1039/c8ob02072h.
PMID:30378620
Abstract
In the present review advances in the metal-catalyzed 1,3-dipolar cycloaddition reactions of nitrile oxides, mainly in the last decade, will be presented and discussed. An overview on the structure, preparation, dimerization and related reactions as well as the relevant aspects in the cycloaddition chemistry of nitrile oxides (including mechanistic aspects) have also been considered.
摘要
在本次综述中，主要介绍和讨论了过去十年中金属催化的腈氧化物 1,3-偶极环加成反应的进展。还概述了腈氧化物的结构、制备、二聚化及相关反应以及偶极环加成化学（包括反应机理）中的相关方面。
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