Castner David G
National ESCA & Surface Analysis Center for Biomedical Problems, Molecular Engineering & Sciences Institute, Departments of Bioengineering & Chemical Engineering, University of Washington, Seattle, WA 98195-1653 USA.
Surf Interface Anal. 2018 Nov;50(11):981-990. doi: 10.1002/sia.6422. Epub 2018 Mar 23.
Surfaces and interfaces play a critical role in material performance in many applications including catalysis, biomaterials, microelectronics, tribology and adhesion. Characterizing the important surfaces and interfaces involved in each application may present different challenges, but the approach to investigating them often is rather similar. Specialized instrumentation is typically used to probe the surface region of a material and often times it is required to develop new instrumentation and data analysis methods to obtain the desired information. It usually best to use multiple experimental techniques, often coupled with theoretical calculations and simulations, to gain a more complete understanding of the surface and interface regions. Careful handling and preparation of the samples is required so the surface is not altered during these processes as well as during analysis. Using model samples with well-defined surface structures and compositions can provide information about fundamental processes as well as help develop the analytical tools and methodology needed to characterize complex surfaces and interfaces. Thus, the expertise and experience a surface analyst acquires in one field can be readily applied to other fields, even when those fields are significantly differently (e.g., biomaterials and microelectronics). This has resulted in surface analysts moving rather easily between different research and application areas. As one example my career path of small molecule chemisorption and reactivity on single crystals to industrial catalysis to biomedical surface science is presented in this manuscript.
表面和界面在包括催化、生物材料、微电子学、摩擦学和粘附等许多应用中的材料性能方面起着关键作用。表征每个应用中涉及的重要表面和界面可能会带来不同的挑战,但研究它们的方法通常相当相似。通常使用专门的仪器来探测材料的表面区域,而且常常需要开发新的仪器和数据分析方法来获取所需信息。通常最好使用多种实验技术,这些技术常常与理论计算和模拟相结合,以便更全面地了解表面和界面区域。需要小心处理和制备样品,这样在这些过程以及分析过程中表面不会被改变。使用具有明确表面结构和组成的模型样品可以提供有关基本过程的信息,还能帮助开发表征复杂表面和界面所需的分析工具和方法。因此,表面分析人员在一个领域获得的专业知识和经验可以很容易地应用于其他领域,即使这些领域有很大差异(例如生物材料和微电子学)。这使得表面分析人员能够相当轻松地在不同的研究和应用领域之间转换。作为一个例子,本文展示了我从单晶上小分子化学吸附和反应性的研究路径,到工业催化,再到生物医学表面科学的职业发展历程。