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胆甾相双扭曲圆柱状胶束的形成和动力学。

Formation and dynamics of the aggregates of cholesteric double-twist cylinders.

机构信息

Faculty of Science and Engineering, Waseda University, Tokyo, Japan.

出版信息

Soft Matter. 2018 Dec 12;14(48):9798-9805. doi: 10.1039/c8sm01565a.

Abstract

We succeeded in driving the unidirectional rigid-body rotation of cholesteric (Ch) double-twist cylinder (DTC) droplets under a heat flux along the cylindrical symmetry axis. To directly observe the rigid-body rotation of DTC droplets, in each of which the center of the rotation and the symmetry axis of the structure correspond, we fabricated DTC aggregates that comprise several DTCs with intact structures. Given a steady heat flux, the DTC aggregates metastabilized by the shape and the surface anchoring show a unidirectional rigid-body rotation with a constant angular velocity. The rotational direction is determined by the molecular chirality and the direction of the heat flux, and the rotational velocity increases with the temperature gradient and decreases with the aggregation number N of the DTCs as 1 + 2/sin2(π/N). The behavior agrees with a simple model based on the linear phenomenological equation.

摘要

我们成功地在沿圆柱对称轴的热流作用下驱动胆甾相(Ch)双扭曲圆柱(DTC)液滴的单向刚体旋转。为了直接观察 DTC 液滴的刚体旋转,我们制造了 DTC 聚集体,其中包含几个结构完整的 DTC。在稳定的热流作用下,由形状和表面锚定稳定的 DTC 聚集体表现出具有恒定角速度的单向刚体旋转。旋转方向由分子手性和热流方向决定,旋转速度随温度梯度增加而增加,随 DTC 的聚集数 N 增加而按 1 + 2/sin2(π/N) 减小。该行为与基于线性唯象方程的简单模型一致。

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