Shao Yue, Jiang Zhiping, Zhang Yunjing, Wang Tongzhou, Zhao Peng, Zhang Zhe, Yuan Jiayin, Wang Hong
Key Laboratory of Functional Polymer Materials, Ministry of Education, Institute of Polymer Chemistry, College of Chemistry , Nankai University , Tianjin 300071 , P.R. China.
College of Chemistry and Chemical Engineering , Northwest Normal University , Lanzhou 730070 , P.R. China.
ACS Nano. 2018 Nov 27;12(11):11704-11710. doi: 10.1021/acsnano.8b07526. Epub 2018 Nov 8.
Herein, we introduce a straightforward, scalable, and technologically relevant strategy to manufacture charged porous polymer membranes (CPMs) in a controllable manner. The pore sizes and porous architectures of CPMs are well-controlled by rational choice of anions in poly(ionic liquid)s (PILs). Continuously, heteroatom-doped hierarchically porous carbon membrane (HCMs) can be readily fabricated via morphology-maintaining carbonization of as-prepared CPMs. These HCMs, as photothermal membranes, exhibited excellent performance for solar seawater desalination, representing a promising strategy to construct advanced functional nanomaterials for portable water production technologies.
在此,我们介绍一种直接、可扩展且与技术相关的策略,以可控方式制造带电多孔聚合物膜(CPM)。通过合理选择聚离子液体(PIL)中的阴离子,可以很好地控制CPM的孔径和多孔结构。接着,通过对制备好的CPM进行形态保持碳化,可以轻松制备杂原子掺杂的分级多孔碳膜(HCM)。这些HCM作为光热膜,在太阳能海水淡化方面表现出优异的性能,代表了一种构建用于便携式水生产技术的先进功能纳米材料的有前景的策略。