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水热法制备负载于泡沫镍和溶液残渣上的 NiCoO 催化剂用于电化学氧气析出反应的比较研究。

A comparative study of NiCoO catalyst supported on Ni foam and from solution residuals fabricated by a hydrothermal approach for electrochemical oxygen evolution reaction.

机构信息

School of Water Resources and Environment, China University of Geosciences (Beijing), Beijing, 100083, P. R. China.

出版信息

Chem Commun (Camb). 2018 Nov 20;54(93):13151-13154. doi: 10.1039/c8cc08251k.

DOI:10.1039/c8cc08251k
PMID:30403229
Abstract

Residuals have rarely been granted attention when employing a hydrothermal approach to prepare binder-free supported catalysts. Using Ni foam supported NiCo2O4 catalyst for oxygen evolution reaction as an example, it was found that the catalytic activity of NiCo2O4 from the residuals loaded on glass carbon is comparable to Ni foam supported NiCo2O4, while the specific activity and turnover frequency value of the former catalyst are many times higher than that of the supported catalyst. In view of sustainability and green development, residuals should be given more attention when catalyst is prepared using the hydrothermal fabrication approach.

摘要

在采用水热法制备无粘结剂负载型催化剂时,很少有人关注残留物。以 Ni 泡沫负载 NiCo2O4 催化剂为例,用于析氧反应,发现负载在玻璃碳上的残留物所制备的 NiCo2O4 的催化活性与 Ni 泡沫负载 NiCo2O4 相当,而前者的比活性和周转频率值是负载型催化剂的许多倍。鉴于可持续性和绿色发展,在采用水热法制备催化剂时,应该更加关注残留物。

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