用非常规路易斯酸十二氯环六硅烷断裂碳-氯键。
Breaking Carbon-Chlorine Bonds with the Unconventional Lewis Acid Dodecachlorocyclohexasilane.
作者信息
Frohlich Matthew T, Anderson Kenneth J, Ugrinov Angel, Boudjouk Philip
机构信息
Department of Chemistry and Biochemistry , North Dakota State University , Fargo , North Dakota 58108 , United States.
出版信息
Inorg Chem. 2018 Dec 3;57(23):14463-14466. doi: 10.1021/acs.inorgchem.8b00631. Epub 2018 Nov 8.
Abstract
c-SiCl functions as a Lewis acid strong enough to abstract chloride ions from 2 mol of triphenylchloromethane to form the salt [Tr][SiCl]. This is the first example of a Lewis acid "hole" breaking a carbon-halogen bond.
摘要
c-SiCl作为一种足够强的路易斯酸，能够从2摩尔三苯基氯甲烷中夺取氯离子，形成盐[Tr][SiCl]。这是路易斯酸“空穴”破坏碳-卤键的首个实例。
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