螺环并双六并六苯并[cd,mn]蒄。
Spiro-fused bis-hexa-peri-hexabenzocoronene.
机构信息
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany.
Institut für Organische Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55099 Mainz, Germany.
出版信息
Chem Commun (Camb). 2018 Dec 14;54(96):13575-13578. doi: 10.1039/c8cc07405d. Epub 2018 Nov 16.
PMID:30444511
Abstract
A spiro-fused hexa-peri-hexabenzocoronene dimer was synthesized, and its physicochemical properties were studied by UV-Vis absorption and emission spectroscopy as well as cyclic voltammetry. Chemical oxidation of SB-HBC afforded its radical cation and dication derivatives, which could be reversibly reduced to the neutral state.
摘要
合成了一种螺环稠合的六并苯六并苯二聚体，并通过紫外-可见吸收和发射光谱以及循环伏安法研究了其物理化学性质。对 SB-HBC 进行化学氧化得到了其自由基阳离子和二阳离子衍生物，这些衍生物可以可逆地还原为中性状态。
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