Aix Marseille Univ, CNRS, Centrale Marseille, IRPHE, Marseille, France.
Soft Matter. 2018 Nov 28;14(46):9498-9510. doi: 10.1039/c8sm01572d.
We address the mechanical effect of rigid boundaries on freezing suspensions. For this we perform the directional solidification of monodispersed suspensions in thin samples and we document the thickness h of the dense particle layer that builds up at the solidification front. We evidence a change of regime in the evolution of h with the solidification velocity V with, at large velocity, an inverse proportionality and, at low velocity, a much weaker trend. By modelling the force balance in the critical state for particle trapping and the dissipation phenomena in the whole layer, we link the former evolution to viscous dissipation and the latter evolution to solid friction at the rigid sample plates. Solid friction is shown to induce an analog of the Janssen effect on the whole layer. We determine its dependence on the friction coefficient between particles and plates, on the Janssen's redirection coefficient in the particle layer, and on the sample depth. Fits of the resulting relationship to data confirm its relevance at all sample depths and provide quantitative determinations of the main parameters, especially the Janssen's characteristic length and the transition thickness h between the above regimes. Altogether, this study thus clarifies the mechanical implication of boundaries on freezing suspensions and, on a general viewpoint, provides a bridge between the issues of freezing suspensions and of granular materials.
我们研究了刚性边界对冻结悬浮液的力学影响。为此,我们在薄样品中进行了单分散悬浮液的定向凝固,并记录了在凝固前沿形成的密集颗粒层的厚度 h。我们发现 h 随凝固速度 V 的演化存在一个模式转变,在大速度下呈反比关系,在低速度下则呈较弱的趋势。通过对颗粒捕获的临界状态下的力平衡和整个层中的耗散现象进行建模,我们将前者的演化与粘性耗散联系起来,将后者的演化与刚性样品板上的固体摩擦联系起来。结果表明,固体摩擦在整个层中引起了类似扬森效应的现象。我们确定了它对颗粒与板之间的摩擦系数、颗粒层中扬森重定向系数以及样品深度的依赖性。对所得关系的拟合数据证实了其在所有样品深度上的相关性,并提供了主要参数的定量确定,特别是扬森特征长度和上述两个模式之间的过渡厚度 h。总的来说,这项研究澄清了边界对冻结悬浮液的力学影响,从更普遍的角度来看,为冻结悬浮液和颗粒材料问题之间架起了一座桥梁。