Zhang Guanyu, Wang Maodie, Fronczek Frank R, Smith Kevin M, Vicente M Graça H
Department of Chemistry , Louisiana State University , Baton Rouge , Louisiana 70803 , United States.
Inorg Chem. 2018 Dec 3;57(23):14493-14496. doi: 10.1021/acs.inorgchem.8b02775. Epub 2018 Nov 19.
A novel and straightforward strategy for boron functionalization in boron dipyrromethenes (BODIPYs) is developed. In particular, this synthetic strategy provides new possibilities for the synthesis of sp N-substituted (B-NCS and -NCO), benzotriazole- and trifluoroacetamide-substituted BODIPYs that were hitherto unknown. These new BODIPYs display an array of highly desirable photophysical properties (0.04 < Φ < 0.86), paving the road for further investigations in material applications.
开发了一种用于硼二吡咯亚甲基（BODIPYs）中硼官能化的新颖且直接的策略。特别地，这种合成策略为合成迄今未知的sp N-取代（B-NCS和-NCO）、苯并三唑和三氟乙酰胺取代的BODIPYs提供了新的可能性。这些新型BODIPYs展现出一系列非常理想的光物理性质（0.04 < Φ < 0.86），为材料应用的进一步研究铺平了道路。
