用于光催化铃木耦合的钯纳米粒子修饰的胶体多孔有机聚合物的开发数据集。

Dataset on the development of palladium nanoparticle decorated colloidal porous organic polymer for photocatalytic Suzuki coupling.

作者信息

Chakraborty Jeet, Nath Ipsita, Verpoort Francis

机构信息

Laboratory of Organometallics, Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Center for Chemical and Material Engineering, Wuhan University of Technology, Wuhan 430070, China.

National Research Tomsk Polytechnic University, Lenin Avenue 30, Tomsk 634050, Russia.

出版信息

Data Brief. 2018 Oct 27;21:1157-1165. doi: 10.1016/j.dib.2018.10.096. eCollection 2018 Dec.

DOI:10.1016/j.dib.2018.10.096

PMID:30456230

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6231033/

Abstract

Herein, we report the synthesis and characterization data of visible-light-active colloidal azobenzene-based porous organic polymer (Azo-POP) and its Pd-nanoparticle loaded analog (Pd-Azo-POP). The setup for photocatalytic Suzuki reactions triggered by Pd-Azo-POP under conventional batch reaction mode as well as in a prototypal continuous flow system has also been provided in addition to the detailed catalytic data including H and C NMR spectra of the obtained products. For further discussions on the materials, their effect on overall catalysis and mechanistic insight, please refer to the associated article "Pd-nanoparticle decorated azobenzene-based colloidal porous organic polymer for visible and natural sunlight-induced Mott-Schottky junction mediated instantaneous Suzuki coupling" (Chakraborty et al., 2019).

摘要

在此，我们报告了可见光活性的基于偶氮苯的胶体多孔有机聚合物（Azo-POP）及其负载钯纳米颗粒的类似物（Pd-Azo-POP）的合成与表征数据。除了所获得产物的H和C NMR光谱等详细催化数据外，还提供了在传统间歇反应模式以及原型连续流系统中由Pd-Azo-POP引发的光催化铃木反应的装置。关于这些材料的进一步讨论、它们对整体催化的影响以及机理见解，请参考相关文章“用于可见光和自然阳光诱导的莫特-肖特基结介导的瞬时铃木偶联的钯纳米颗粒修饰的基于偶氮苯的胶体多孔有机聚合物”（Chakraborty等人，2019年）。