Theoretical comparison of the excitation efficiency of waveguide and surface plasmon modes between quantum-mechanical and electromagnetic optical models of organic light-emitting diodes.

We theoretically compare the excitation efficiency of waveguide and surface plasmon modes between quantum-mechanical and classical electromagnetic optical models of organic light-emitting diodes (OLEDs). A sophisticated optical model combining the two approaches is required to obtain an accurate calculation result and a comprehensive understanding of the micro-cavity effect in OLEDs. In the quantum-mechanical approach based on the Fermi's golden rule, the mode expansion method is used to calculate the excitation efficiency. In the classical electromagnetic approach, the spectral power density calculated by the point dipole model is fitted by the summation of the Lorentzian line shape functions, which provide the excitation probability of each waveguide and surface plasmon modes. The mode coupling efficiencies on the basis of the two approaches are calculated in a bottom-emitting OLED when the position of a dipole emitter is varied. By comparing the calculation results, we confirm the equivalence of two approaches and obtain the better optical interpretation to the calculated excitation efficiency of waveguide and surface plasmon modes. The ratio of mode excitation efficiencies calculated by two approaches agrees well with each other except the contribution of the near-field absorption component.